Publicaciones Seleccionadas
2014:
"Novel
ortho-ope metallofoldamers: binding-induced
folding promoted by nucleating Ag(I)-alkyne
interactions" A.
Martín-Lasanta, L. Álvarez de Cienfuegos, A.
Johnson, D. Miguel, A. J. Mota, A. Orte, M. J.
Ruedas-Rama, M. Ribagorda, D. J. Cárdenas, M.
C. Carreño, A. M. Echavarren, J. M. Cuerva
Chem. Sci. 2014, 5,
4582-4591.
-"Structural versus electrical
functionalization of oligo(phenylene
ethynylene) diamine molecular junctions" M. T.
González, X. Zhao, D. Z. Manrique, D. Miguel,
E. Leary, M. Gulcur, A. S. Batsanov, G. Rubio-Bollinger,
C. J. Lambert, M. R. Bryce, N. Agraït J.
Phys. Chem. C 2014, 118,
21655–21662.
-"Rational design of a new
fluorescent ‘ON/OFF’ xanthene dye for
phosphate detection in live cells" A.
Martínez-Peragón, D. Miguel, A. Orte, A. J.
Mota, M. J. Ruedas-Rama, J. Justicia, J. M.
Álvarez-Pez, J. M. Cuerva, L. Crovetto Org.
Biomol. Chem. 2014, 12,
6432-6439.
-"Ti(III)-catalyzed
cyclizations of ketoepoxypolyprenes: Control
over the number of rings and unexpected
stereoselectivities" S. P. Morcillo, D.
Miguel, S. Resa, A. Martín-Lasanta, A. Millán,
D. Choquesillo-Lazarte, J. M. García-Ruiz, A.
J. Mota, J. Justicia, J. M. Cuerva. J. Am.
Chem. Soc. 2014,
136, 6943−6951.
-"Cp2TiCl-catalyzed
highly stereoselective intramolecular epoxide
allylation using allyl carbonates" I.
Rodríguez-Márquez, A. Millán, A. G. Campaña,
J. M. Cuerva Org.
Chem. Front. 2014,
1, 373-381.
-"Ti/Ni-mediated inter and
intramolecular conjugate addition of aryl and
alkenyl halides and triflates" I.
Rodríguez-Márquez, D. Miguel, A. Millán, M. L.
Marcos, L. Álvarez de Cienfuegos, A. G.
Campaña, J. M. Cuerva J. Org. Chem.
2014, 79, 1529–1541.
-"Highly regioselective and chemoselective
titanocene mediated Barbier-type allylations"
S. P. Morcillo, A. Martínez-Peragón, V. Jakoby,
A. J. Mota, C. Kube, J. Justicia, J. M.
Cuerva, A. Gansäuer Chem.
Commun. 2014,
50, 2211-2213.
-"Recent applications of Cp2TiCl in
natural product synthesis" S. P. Morcillo, D.
Miguel, A. G. Campaña, L. Álvarez de
Cienfuegos, J. Justicia, J. M. Cuerva Org.
Chem. Front. 2014,
1, 15-33.
-"Synthesis and
photophysics of a new family of fluorescent 9-alkyl
substituted xanthenones" A. Martínez-Peragón,
D. Miguel, R. Jurado, J. Justicia, J. M.
Álvarez-Pez, J. M. Cuerva, L. Crovetto Chem.,
Eur. J. 2014,
20, 447-455.
2013:
-"The role of water-based
hydrogen atom wires in long range electron
transfer reactions in aqueous media for the
Fe(II)-Fe(III) self-exchange and related
systems" A. G. Campaña, E. Buñuel, J. M.
Cuerva, D. J. Cárdenas Chem.,
Eur. J. 2013,
19, 16187-16191.
-"Titanocene(III)-catalyzed 6-exo
versus 7-endo cyclizations of
epoxypolyprenes: Efficient control and
synthesis of versatile terpenic building
blocks" J.
Justicia, T. Jiménez, D.
Miguel, R.
Contreras-Montoya, R.
Chahboun, E. Álvarez-Manzaneda,
Daniel Collado-Sanz, D.
J. Cárdenas, J. M.
Cuerva Chem.,
Eur. J. 2013,
19, 14484-14495.
2012:
-"Water control over the
chemoselectivity of Ti/Ni multimetallic system:
Heck- or reductive-type cyclization reactions
of alkyl iodides" A. Millán, L. Álvarez de
Cienfuegos, D. Miguel, A. G. Campaña, J. M.
Cuerva
Org.
Lett.
2012, 14, 5984-5987.
-"A versatile bottom-up
approach to stapled -conjugated
helical scaffolds: Synthesis and chiroptical
properties of cyclic o-phenylene ethynylene
oligomers" N. Fuentes, A. Martín-Lasanta, L.
Álvarez de Cienfuegos, R. Robles, D.
Choquesillo-Lazarte, J. M. García-Ruiz, A. J.
Mota, L. Martínez-Fernández, I. Corral, D. J.
Cárdenas, M. Ribagorda, M. C. Carreño, J. M.
Cuerva Angew. Chem. Int.
Ed. 2012, 51, 13036-13040.
-"Thermal-driven nanofuses
based on organometallic rotors" A. J. Mota, L.
Álvarez de Cienfuegos, S. P. Morcillo, N.
Fuentes, D. Miguel, S. Rodríguez-Bolívar, F.
M. Gómez-Campos, D. J. Cárdenas, J. M. Cuerva
ChemPhysChem 2012, 13, 3857-3865.
-"Dichlorobis(cyclopentadienyl)titanium"
D. Miguel, A. G. Campaña, J. Justicia, J. M.
Cuerva e-EROS Encyclopedia of
Reagents for Organic Synthesis 2012,
aceptada.
-"Clarifying the structure of
granadaene: Total synthesis of related
analogue [2]-granadaene and confirmation of
its absolute stereochemistry" M. Paradas, R.
Jurado, A. Haidour, J. Rodríguez Granger, A.
Sampedro Martínez, M. de la Rosa Fraile, R.
Robles, J. Justicia, J. M. Cuerva
Bioorg. Med. Chem.
2012, 20, 6655-6661.
-"Combining the Power of TiIII-mediated
Processes for an Easy Access to Hydroxylated
Polycyclic Terpenoids. Synthesis of
Sesterstatin 1 and C-D Rings of Aspergilloxide"
T.
Jiménez, S.
P. Morcillo, A.
Martín-Lasanta, D.
Collado-Sanz, D.
J. Cárdenas,
A.
Gansäuer, J.
Justicia, J.
M. Cuerva Chem.,
Eur. J. 2012,
18,
12825-12833.
-"Model System for Cell
Adhesion Mediated by Weak Carbohydrate−Carbohydrate
Interactions" B. Lorenz, L. Álvarez de
Cienfuegos, M. Oelkers, E. Kriemen, C. Brand,
M. Stephan, E. Sunnick, D. Yüksel, V. Kalsani,
K. Kumar, D. B. Werz, A. Janshoff J. Am. Chem. Soc.
2012, 134,
3326-3329.
-"Ti/Ni-Based Multimetallic
System for the Efficient Allylation of
Carbonyl Compounds" A. Martínez-Peragón, Alba
Millán, A. G. Campaña, I. Rodríguez-Márquez,
S. Resa, D. Miguel, L. Álvarez de Cienfuegos,
J. M. Cuerva
Eur. J. Org. Chem.
2012,
1499-1503.
-"Influence of the Number of
Anchoring Groups in the Electronic and
Mechanical Properties of Benzene-, Anthracene-
and Pentacene-Based Molecular Devices" A.
Martín-Lasanta, D. Miguel, T. García, J. A.
López-Villanueva, S. Rodríguez-Bolivar, F. M.
Gómez-Campos, E. Buñuel, D. J. Cárdenas, L.
Álvarez de Cienfuegos, J. M. Cuerva
ChemPhysChem 2012, 13,
860-868.
-"H2O-Activation
for HAT: Correct Structures and Revised
Mechanisms" A. Gansäuer, A. Cangönül, M.
Behlendorf, C. Kube, J. M. Cuerva, J.
Friedrich, M. van Gastel Angew. Chem. Int.
Ed. 2012, 51, 3266–3270.
2011:
-"on/off
Electrochemical Switches
Based on
Quinone-Bisketals"
N. Fuentes, L. Álvarez de Cienfuegos,
A. Parra, D. Choquesillo-Lazarte, J. M.
García-Ruiz, M. L. Marcos, E. Buñuel, M.
Ribagorda, M. C. Carreño, D. J. Cárdenas, J.
M. Cuerva Chem. Commun. 2011,
47, 1586-1588. This article has received an special
metion in the journal Chemicals&Engineering
News (see
here).
-"Titanium/Palladium-Mediated
Regioselective
Propargylation of Ketones
Using Propargylic
Carbontates as
Pronucleophiles"
A. Millán, L. Álvarez
de Cienfuegos, A.
Martín-Lasanta, A. G.
Campaña, J. M. Cuerva
Adv. Synth.
Catal. 2011,
353,
73-78.
-"Ti/Pd
Bimetallic Systems for the Efficient
Allylation of Carbonyl Compounds and
Homocoupling reactions"
A. Millán, A. G.
Campaña, B. Bazdi, D. Miguel, L.
Álvarez
de Cienfuegos, A. M.
Echavarren, J. M. Cuerva
Chem.,
Eur. J. 2011,
17,
3985-3994.
-"Titanocene(III)-Promoted
Barbier-type Crotilation of Carbonyl Compounds"
I. Sancho-Sanz, D. Miguel, A. Millán, R. E.
Estévez, J. L. Oller-López, E. Álvarez-Manzaneda,
R. Robles, J. M. Cuerva, J. Justicia J. Org. Chem.
2011, 76, 732-735.
-"Conductance
and Application of
Organic
Molecule Pairs as
Nanofuses" S.
Rodríguez-Bolívar, F.
M. Gómez-Camposa, L.
Álvarez de Cienfuegos,
N. Fuentes, D.
J. Cárdenas, E. Buñuel,
J. E. Carcellera, A.
Parra, J. M. Cuerva
Phys. Rev. B
2011, 83,
125424/1-125424/11.
-"Mild Method for the
Selective Esterification of Carboxylic Acids
Based on the Garegg-Samuelsson Reaction"
S. Morcillo, L. Álvarez de Cienfuegos, A. J.
Mota, J. Justicia, R. Robles J. Org. Chem.
2011, 76, 2277-2281.
-"Bioinspired
Terpene
Synthesis: a Radical
Approach"
J. Justicia, L. Álvarez de Cienfuegos, A. G.
Campaña, D. Miguel, V. Jakoby, A. Gänsauer, J.
M. Cuerva Chem. Soc. Rev. 2011,
40, 3525-3537.
-"Reduction Reactions in water,
supercritical CO2 and ionic liquids as green
solvents" L. Álvarez de Cienfuegos, R.
Robles, D. Miguel, J. Justicia, J. M. Cuerva
Chem. Sus. Chem. 2011, 4,
1035-1048.
-"Water-based Hydrogen-Atom
Wires as Mediators in Long-Range Proton-Coupled
Electron Transfer in Enzymes: a New
Twist on Water Reactivity" D. J.
Cárdenas, J. M. Cuerva, M. Alías, E.
Buñuel, A. G. Campaña Chem. Eur.
J. 2011,
17, 8318–8323.
-"Organic-based
Molecular
Switches for Molecular
Electronics" N.
Fuentes, A.
Martín-Lasanta, L.
Álvarez de Cienfuegos, M.
Ribagorda, A.
Parra, J. M. Cuerva
Nanoscale 2011, 3,
4003-4014.
-"Ti/Pd-Promoted
Intramolecular Michael-type Addition of
Allylic Carboxylates to Activated Alkenes"
A. Millán,
A. Martín-Lasanta, D.
Miguel, L. Álvarez de
Cienfuegos, J.
M. Cuerva Chem. Commun. 2011,
47, 10470-10472.
2010:
-"Unprecedented H-Atom
Transfer from Water to Ketyl Radicals mediated
by Cp2TiCl"
M. Paradas, A. G. Campaña, M. L. Marcos, J. Justicia,
A. Haidour, R. Robles, D. J. Cárdenas, J. E. Oltra, J. M.
Cuerva Dalton Trans.,
2010,
39, 8796-8800.
-"Understanding
the Exceptional Hydrogen-Atom Donor
Characteristics of Water in TiIII-Mediated
Free-Radical Chemistry"
M. Paradas, A. G. Campaña, T. Jiménez, R.
Robles, J. E. Oltra, E. Buñuel, J. Justicia,
D. J. Cárdenas, J. M.
Cuerva J. Am. Chem. Soc.
2010, 132,
12748-12756.
-"Mn(0)-Mediated
Chemoselective Reduction of Aldehydes.
Application to the Synthesis of
a-Deuterioalcohols"
T. Jiménez, E. Barea, J. E. Oltra, J. M.
Cuerva, J. Justicia J. Org. Chem.
2010, 75, 7022-7025.
-"Radical
Reduction of Epoxides Using a
Titanocene(III)/Water System: Synthesis of
β-Deuterated
Alcohols and Their Use as Internal Standards
in Food Analysis"
T. Jiménez, A. G. Campaña, B. Bazdi, M.
Paradas, D. Arráez-Román, A. Segura-Carretero,
A. Fernández-Gutiérrez, J. E. Oltra, R.
Robles, J. Justicia, J. M. Cuerva Eur. J.
Org. Chem. 2010, 4288-4295.
2009:
-"Ti-Catalyzed Barbier-type
Allylations and Related Reactions" R. E.
Estévez, J. Justicia, B. Bazdi, N. Fuentes, M.
Paradas, D. Choquesillo-Lazarte, J. M.
García-Ruiz, R. Robles, A. Gansäuer, J. M. Cuerva, J. E.
Oltra Chem.,
Eur. J. 2009,
15,
2774-2791.
-"Unexpected TiIII/Mn-Promoted
Pinacol Coupling of Ketones" M.
Paradas, A. G. Campaña, R. E. Estévez, L.
Älvarez de Cienfuegos, T. Jiménez, R. Robles, J. M. Cuerva, J. E.
Oltra J. Org.
Chem. 2009,
74,
3616-3619.
-"Efficient Propargylation of
Aldehydes and Ketones Catalyzed by
Titanocene(III)" J. Justicia, I. Sancho-Sanz,
E. Álvarez-Manzaneda, J. E. Oltra, J. M.
Cuerva Adv. Synth.
Catal. 2009,
351,
2295-2300.
-"Mixed
Disproportionation versus Radical Trapping in
Titanocene(III)-Promoted Epoxide Openings"
J. Justicia, T. Jiménez, S. P. Morcillo, J. M.
Cuerva, J. E. Oltra Tetrahedron 2009,
65, 10837-10841.
2008:
-"Ti-Catalyzed
Reformatsky-Type Coupling between
 -Halo
Ketones and Aldehydes"
R. E. Estévez, M.
Paradas, A. Millán, T. Jiménez, R. Robles, J.
M. Cuerva, J. E. Oltra J.
Org. Chem. 2008, 73,
1616-1619.
-"Titanium-Catalyzed Enantioselective
Synthesis of a-Ambrinol"
J. Justicia, A. G. Campaña, B. Bazdi, R.
Robles, J. M. Cuerva, J. E. Oltra Adv. Synth.
Catal. 2008, 350, 571-576.
-"Divergent Titanium-Mediated
Allylations with Modulation by Nickel or
Palladium" A. G. Campaña, B. Bazdi, N.
Fuentes, R. Robles, J. M. Cuerva, J. E. Oltra,
S. Porcel, A. M. Echavarren Angew. Chem.
Int. Ed. 2008, 47,
7515-7519.
-"Ti-catalysed
transannular cyclization of
epoxygermacrolides. Synthesis of antifungal
(+)-tuberiferine and
(+)-dehydrobrachylaenolide"
J. Justicia, L. Álvarez de Cienfuegos, R. E.
Estévez, M. Paradas, A. M. Lasanta, J. L.
Oller, A. Rosales, J. M. Cuerva, J. E. Oltra
Tetrahedron 2008, 64,
11938-11943.
2007:
-"Unprecedented Hydrogen Transfer from Water
to Alkenes and Alkynes Mediated by Ti(III) and
Late Transition Metals" A. G. Campaña, R. E.
Estévez, N. Fuentes, R. Robles, J. M. Cuerva,
E. Buñuel, D. Cardenas, J. E. Oltra Org. Lett.
2007, 9, 2195-2198.
-"Sodium Tetramethoxyborate: An Efficient
Catalyst for Michael Additions of Stabilized
Carbon Nucleophiles" A. G. Campaña, N.
Fuentes, E. Gómez-Bengoa, C. Mateo, J. E.
Oltra, A. M. Echavarren, J. M. Cuerva J.
Org. Chem. 2007, 72,
8127-8130.
2006: -"Cp2TiCl in Natural Product
Synthesis" J. M. Cuerva, J. Justicia, J. L.
Oller-López , J. E. Oltra Top. Curr. Chem.
2006, 264, 63-91.
-"Water: The Ideal Hydrogen-Atom Source in
Free-Radical Chemistry Mediated by Ti(III)
and Other Single-Electron-Transfer Metals?"
J. M. Cuerva, A. G. Campaña, J. Justicia, A.
Rosales, J. L. Oller-López, R. Robles, D. J.
Cardenas, E. Buñuel, J. E. Oltra Angew.
Chem. Int. Ed. 2006, 45,
5522-5526.
-"Stereocontrolled
Coupling between Aldehydes and Conjugated
Alkenals Mediated by TiIII/H2O"
R. E. Estévez, J. L. Oller-López, R.
Robles, C. R. Melgarejo, A. Gansäuer, J.
M. Cuerva, J. E. Oltra Org. Lett.
2006, 8, 5433-5436.
2005:
-"Enantiospecific Strategy Towards Oxygen-Bridged
Terpenoids: Tandem Transannular-Cyclization
and Ring-Contraction Processes" A. Rosales, R.
E. Estévez, J. M. Cuerva, J. E. Oltra.
Angew. Chem. Int. Ed. 2005, 44,
319-322.
-"Convenient Synthesis of Nucleosides and
Isonucleoside Analogues" L. Álvarez de
Cienfuegos; A. J. Mota, R. Robles. Org.
Lett. 2005, 7, 2161-2164.
-"Exploiting Pd(II) and Ti(III) Chemistry To
Obtain g-Dioxygenated
Terpenoids: Synthesis of Rostratone and Novel
Approaches to Aphidicolin and Pyripyropene A"
J. Justicia, J. E. Oltra, J. M. Cuerva J.
Org. Chem. 2005, 70,
8265-8272.
-"7-endo
Radical Cyclizations Catalyzed by
Titanocene(III). Straightforward Synthesis
of Terpenoids with Seven-Membered
Carbocycles" J. Justicia, J. L. Oller-López,
A. G. Campaña, J. E. Oltra, J. M. Cuerva, E.
Buñuel, D. J. Cárdenas J. Am. Chem. Soc.
2005, 127, 14911-14921.
2004:
-"Titanocene-Catalyzed Cascade Cyclization of
Epoxypolyprenes: Straightforward Synthesis of
Terpenoids by Free-Radical Chemistry" J.
Justicia, A. Rosales, E. Buñuel, J. L. Oller-López,
M. Valdivia, A. Haïdour, J. E. Oltra, A. F.
Barrero, D. J. Cardenas, J. M. Cuerva. Chem.,
Eur. J. 2004, 10, 1778-1788.
-"General Approach to Polycyclic
Meroterpenoids Based on Stille Couplings and
Titanocene Catalysis" J. Justicia, J. E.
Oltra, J. M. Cuerva. J. Org. Chem.
2004, 69, 5803-5086.
-"Unprecedented Barbier-type Reactions
Catalysed by Titanocene(III)" A. Rosales, J.
L. Oller-López, J. Justicia, A. Gansäuer, J.
E. Oltra, J. M. Cuerva Chem. Commun.
2004, 2628-2629.
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